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selenium rectifier : ウィキペディア英語版 | selenium rectifier
A selenium rectifier is a type of metal rectifier, invented in 1933. They were used in power supplies for electronic equipment, and in high current battery charger applications until they were superseded by silicon diode rectifiers in the 1970s. The photoelectric and rectifying properties of selenium were observed by C. E. Fitts around 1886 but practical rectifier devices were not manufactured routinely until the 1930s. Compared with the earlier copper oxide rectifier, the selenium cell could withstand higher voltage but at a lower current capacity per unit area.〔Peter Robin Morris ''A history of the world semiconductor industry'', IET, 1990 ISBN 0-86341-227-0 pages 13, 18〕 ==Construction==
Selenium rectifiers are made from stacks of aluminum or steel plates coated with about 1 μm of bismuth or nickel. A much thicker layer of selenium (50 to 60 μm) which has been doped with a halogen is deposited on top of the thin metal plating. The selenium is then converted into polycrystalline gray (hexagonal) form by annealing. Each plate is able to withstand about 20 volts in the reverse direction. The metal squares, or disks, also serve as heat sinks in addition to providing a mounting place for the selenium disks. Plates can be stacked indefinitely to withstand higher voltages. Stacks of thousands of miniature selenium disks have been used as high voltage rectifiers in television sets and photocopy machines.
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